| CHEMISTRY1998
Solved Question Papers
All correct answers are given in green |
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| Questions |
| 1. |
The acid which reduces Fehling's solution is :
a) Ethanoic
acid.
b) Methanoic
acid.
c) Propanoic
acid.
d) Butanoic
acid. |
| 2. |
When 0.5g. of sulphur is burnt to SO2 4.6 kj of heat is
liberated. What is the enthalpy of formation of sulphur dioxide? (S=32
and O=16)
a) -147.2KJ
b) +
147.2KJ
c) +
294.4KJ
d) - 294.4KJ. |
| 3.
|
Assuming complete ionisation, the pH of 0.1M HCL is 1. The molarity
of H2SO4 with the same Ph is:
a) 0.1
b) 0.2
c) 0.05
d) 2.0 |
| 4. |
The double helical structure of DNA was proposed by:
a) Meicher
b)
Wastson and Crick
c) Khorana
d) Emil Fischer.
|
| 5.
|
Oxygen contains 90% O16 abd 10% O18 Its atomic
mass is:
a)
16.2
b) 17.4
c) 17.
d) 16.5.
|
| 6. |
Which of the following is used for inducing sleep ?
a) chloroquine
b) paracetamol
c)
barbituric acid derivatives.
d) bithional |
| 7. |
The colour of the precipitate produced by adding NaOH solution to
HgCl2 is :
a) black
b)
yellow
c) white
d) brown.
|
| 8. |
Which of the following is used as a catalyst for preparing Grignard
reagent ?
a)
iodine power
b) iron power
c) manganese
dioxide
d) activated
charcoal. |
| 9. |
Acetone and acetophenone can be distinguished by :
a) Tollens
test
b) CNP TEST
c) Schiff's
regent
d)
saturated solution of NaHSO3. |
| 10.
|
When chlorine reacts with ethyl alcohol, it forms:
a) chloroform
b)
chloral
c) ethyl
chloride
d) carbon
tetrachloride. |
| 11. |
The long form of the periodic table has _______ periods, and _______vertical
columns.
a) 6;8
b) 6;18
c) 8;12
d)
7;18
|
| 12. |
In the Fischer - Tropsch synthesis of petrol, _____and _____ are
used as the
raw materials.
a) CH4;H2
b)
H2 ; CO
c) CH3OH;CO
d) CH4;CH3OH.
|
| 13. |
Conversion of CH4 to CH3Cl is an example of ______ reaction .
a) nucleophilic substitution
b) electrophilic substitution
c) Free radical addition
d)
Free radical substitution. |
| 14 |
In benzene, all the six C-C bonds have the same length because of
:
a) Isomerism
b) chain
isomerism
c)
resonance
d) hybridisation. |
| 15. |
The element used by Rutherford in his famous scattering experiment
was :
a) tin
b)
gold
c) lead
d) silver |
| 16. |
Which hydrocarbon is formed by the action of sodium on ethyl bromide?
a) Methane
b) Ethane
c)
Butane
d) isobutane. |
| 17. |
Acetone and acetaldehyde are:
a) functional isomer
b) position-isomers
c) chain isomers
d)
not isomers. |
| 18. |
What is the volume of 0. 1 N HCL required to react completely with
1.0g. of pure
calcium carbonate ? (Ca=40, c=12 and O=16)
a) 250 cm3
b) 150 cm3
c) 100 cm3
d)
200 cm3 |
| 19. |
Liebermann's test is answered by :
a) methylamine
b) aniline
c)
phenol
d) ethyl
benzoate |
| 20.
|
Which of the following compounds does not undergo nucleophilic substitution
reaction ?
a) ethyl bromide
b)
vinyl chloride
c) isopropyl
chloride
d) benzyl chloride. |
| 21. |
A segment of DNA molecule which codes or specifies for one polypeptide
chain is called______?
a) Adenine
b) phosphate
group
c) amino acid
d)
gene |
| 22. |
Vanaspathi is prepared by the ___________of vegetable oils. |
| 23. |
Which one of the following is an extensive property?
a) Molarity
b) molar
volume
c) mole
fraction
d) number
of moles |
| 24. |
Which of the following is a linear polymer ?
a) glycogen
b) amylopectin
c)
amylose
d) starch. |
| 25. |
When sodium benzenesulphonate is fused with NaOH, followed by cidification
with
HCl, the product formed is :
a) benzensulphonic
acid
b) sodium
c) phenol
d) chlorobenzene |
| 26. |
When the temperature of an ideal gas is increased from 270C
to 9270C, the kinetic
energy will be:
a) same
b) eight times
c)
four times
d) twice |
| 27. |
Gibbs free energy G is defined as :
a)
G = H - TS
b) G = H + TS
c) G = E + TS
d) G =
E - TS |
| 28. |
The change in entropy of an ideal gas during a reversible isothermal
expansion is :
a) Negative
b)
Positive
c) Zero
d) infinity |
| 29. |
An organic compound is found to contain C = 54.5% O = 36.4% and H
= 9.1% by
mass. Its empirical formula is :
a) C2O
b) CHO2
c)
C2H4O
d) C3H4O |
| 30. |
For the reaction :H2 + CL2 (Sunlight)
® 2HCl taking place on water,the order of
reaction is :
a) 2
b) 1
c)
0
d) 3 |
| 31.
|
Benzene is unreactive because :
a) It has carbon - carbon single bonds
b) It has double bonds
c)
p electrons are delocalised
d) Carbons
are sp2 hybridised |
| 32.
|
What is the monomer of polypeptide ?
a) Glucose
b)
amino acid
c) nucleotide
d) nucleoside |
| 33. |
For the reaction A ® B, the rate increases
by a factor of 2.25 when the concentration of A is increased by 1.5.
What is the order of the reaction ?
a) 0
b) 3
c) 1
d)
2 |
| 34.
|
Which of the following compounds is used in antiknock compositions
to prevent the
deposition of oxides of lead on spark plug combustion chamber
and exhaust pipe
a) glycol
b) glycerol
c) benzene
d) 1,2-dibromoethane
|
| 35.
|
The rate constant of a reaction depends on :
a)
the temperature of the system
b) the time of reaction
c) the
extent of reaction
d) the initial concentration of the reactants |
| 36. |
If a mixture containing 3 moles of hydrogen and 1 mole of nitrogen
is converted
completely into ammonia, the ratio of initial and final volumes at
the same temperature
and pressure would be :
a) 1:2
b)
2:1
c) 1:3
d) 3:1 |
| 37. |
Man dies in an atmosphere of carbon monoxide because:
a) it combines
with oxygen present in the body to form carbon dioxide
b) it increases the blood pressure.
c) it reduces the organic batter of tissues.
d)
it combines with haemoglobin of the blood making it incapable of absorbing
oxygen |
| 38.
|
India conducted an underground nuclear test at :
a)
Narora
b) Tarapura
c) Pushkar
d) Pokhran |
| 39. |
Which of the following enzymes is not useful in the digestion of
proteins ? a) Pepsin
b) Chymotrypsin
c)
Lipase
d) trypsin
|
| 40. |
p-type silicon is formed by adding a minute amount of an element
with :
a)
three valence electrons
b) five valence electrons
c) four valence electrons
d) six valence electrons |
| 41. |
In blast furnace, the highest temperature is in :
a) slag zone
b) reduction zone
c) combustion zone
d) fusion zone |
| 42. |
Silica is added to roasted copper ore during smelting in order to
remove:
a) cuprous
oxide
b) _cuprous
sulphide
c) ferrous sulphide
d)
ferrous oxide |
| 43.
|
Which of the following is an anti diabetic drug ?
a) pencillin
b)
insulin
c) aspirin
d) chloroquine |
| 44. |
Dimethyl terephthalate and ethylene glycol react to form :
a) nylon-66
b) nylon-6
c) neoprene
d)
dacron |
| 45.
|
The internal energy of a substance:
a) decreases with increase in temperature
b)
increases with increase in temperature
c) remains unaffected with change in temperature.
d) can
be calculated by the relation
E = mc2 |
| 46. |
The edge length of the unit cell of NaCl crystal lattice is 552 pm.
If the ionic radius of sodium ion is 95 pm., what is the ionic radius
of chloride ion ? a) 368 pm
b) 190 pm
c) 276 pm
d)
181 pm |
| 47. |
A reagent used to test the presence of Fe+2 ion is :
a) NH4CNS
b) H2S
c)
K3Fe(CN)6
d) K4Fe(CN)6. |
| 48. |
Which of the following is a wrong statement about cast iron ?
a) it contains about 4.5% of carbon
b) it
is also called pig iron
c) it
contracts on cooling
d)
it is corrosion resistant |
| 49. |
What is the product formed in the following reaction ?
 a)
O-hydroxybenzoic acid.
b) p-hydroxybenzoic acid.
c) salicyladehyde.
d) benzaldehyde. |
| 50. |
Amines behave as :
a)Lewis
acids
b)Lewis
bases
c)Amphoteric compounds
d)Neutral compounds |
51. |
he half - life period t½ of a radioactive element is N
years. The eriod of its complete decay is :
a)2 N
years
b)N2 Years
c)infinity
d)½ N2 Years |
| 52. |
Iron pipes laying under acidic soil are often attached to blocks
of magnesium for protection form rusting.Magnesium offers protection
to iron against Corrosion because it
a) is
lighter than iron.
b)
is more readily converted into positive ions.
c )prevents air from reaching the surface of iron.
d) form
a corrosion-resistant ally with iron. |
| 53. |
An aqueous solution containing 100grams of dissolved MgSO4
is fed to a crystallizer where 80% of the Dissolved salt crystallises
out as MgSO4. 6H2O Crystals. How many grams
of the hexahydrate salt Crystals are obtained from the crystalliser?(given
Mg=24; S=32; O=16 and H=1).
a) 80.
b)
152.
c) 120.
d) 100. |
| 54.
|
The most efficient agent for the absorption of SO3 is:
a) 80%
H2S04.
b)
98% H2S04.
c) 90%
H2S04.
d) 20%
H2S04. |
| 55. |
During the electrolysis of fused sodium chloride,the anodic reaction
is :
a) Oxidation of sodium ions
b) reduction of sodium ions
c)
oxidation of chloride ions
d) reduction of chloride ions
|
| 56. |
If the dispersed phase is liquid and the dispersion medium is solid,
the colloid is known as a/an :
a) sol
b) emulsion
c)
gel
d) foam |
| 57.
|
Only an aldehyde having ____can undergo the aldol condensation.
a)
at least one alpha H atom.
b) at
least one beta H atom.
c) no
alpha H atom.
d) an
aromatic ring. |
| 58.
|
Treatment of benzoic acid with Cl2/FeCl3 will give________ acid.
a) o-chlorobenzoic.
b) p-chlorobenzoic.
c)
m-chlorobenzoic.
d) 2,4-dichlorobenzoic. |
| 59.
|
Ribose is an example of a/an: a)
aldopentose.
b) ketohexose.
c) aldohexose.
d) disaccharide. |
| 60. |
The colour of the flame in borron trifluoride test is :
a) blue.
b) crimson.
c) golden
yellow.
d)
green |